Processing of Solid Solution, Mixed Uranium/Refractory Metal Carbides for Advanced Space Nuclear Power and Propulsion Systems; A Dissertation Presented to the Graduate School of the University of Florida in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy

Verlag: University of Florida, Gainesville, FL, 2000

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vii, 167 pages, sheets printed on one side only. Illustrations with color. Clear plastic sheets protect the front and back covers. This work was performed in the Ultra-High Temperature Materials Laboratory of the Innovative Nuclear Space Power and Propulsion Institute (INSPI) at the University of Florida. This study examined the processing technologies and optimal parameters necessary to fabricate samples of single phase, solid solution, mixed uranium/refractory metal carbides. This study was undertaken to develop and optimize processing techniques for producing high density, solid solutions of the mixed carbide (U, Zr, Nb)C, containing five to ten mole percent carbide (UC). The higher uranium density of carbide fuels permits the design of more compact reactor cores. The author in 2022 was serving as Interim Chair and Professor, Mechanical Engineering Program Director, Nuclear Engineering Graduate Program at the University of South Carolina. His reported research interests were in the areas of Advanced nuclear fuels and materials, Nuclear safeguards, Nuclear fuel cycle, Alternative uses of nuclear power including hydrogen, space nuclear power and propulsion. Dissertation Abstract: Nuclear thermal propulsion (NTP) and space nuclear power are two enabling technologies for the manned exploration of space and the development of research outposts in space and on other planets such as Mars. Advanced carbide nuclear fuels have been proposed for application in space nuclear power and propulsion systems. This study examined the processing technologies and optimal parameters necessary to fabricate samples of single phase, solid solution, mixed uranium/refractory metal carbides. In particular, the pseudo-ternary carbide, UC-ZrC-NbC, system was examined with uranium metal mole fractions of 5% and 10% and corresponding uranium densities of 0.8 to 1.8 gU/cc. Efforts were directed to those methods that could produce simple geometry fuel elements or wafers such as those used to fabricate a Square Lattice Honeycomb (SLHC) fuel element and reactor core. Methods of cold uniaxial pressing, sintering by induction heating, and hot pressing by self-resistance heating were investigated. Solid solution, high density (low porosity) samples greater than 95% TD were processed by cold pressing at 150 MPa and sintering above 2600 K for times longer than 90 min. Some impurity oxide phases were noted in some samples attributed to residual gases in the furnace during processing. Also, some samples noted secondary phases of carbon and UC2 due to some hyperstoichiometric powder mixtures having carbon-to-metal ratios greater than one. In all, 33 mixed carbide samples were processed and analyzed with half bearing uranium as ternary carbides of UC-ZrC-NbC. Scanning electron microscopy, x-ray diffraction, and density measurements were used to characterize samples. Samples were processed from powders of the refractory mono-carbides and UC/UC2 or from powders of uranium hydride (UH3), graphite, and refractory metal carbides to produce hypostoichiometric mixed carbides. Samples processed from the constituent carbide powders and sintered at temperatures above the melting point of UC showed signs of liquid phase sintering and were shown to be largely solid solutions. Pre-compaction of mixed carbide powders prior to sintering was shown to be necessary to achieve high densities. Hypostoichiometric, samples processed at 2500 K exhibited only the initial stage of sintering and solid solution formation. Based on these findings, a suggested processing methodology is proposed for producing high density, solid solution, mixed carbide fuels. Pseudo-binary, refractory carbide samples hot pressed at 3100 K and 6 MPa showed comparable densities (approximately 85% of the theoretical value) to samples processed by cold pressing and sintering at temperatures of 2800 K. Presumed First Edition, First printing of only a few copies made.…

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Bibliografische Details

Titel
Processing of Solid Solution, Mixed Uranium/Refractory Metal Carbides for Advanced Space Nuclear Power and Propulsion Systems; A Dissertation Presented to the Graduate School of the University of Florida in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy
Autor
Knight, Travis Warren
Verlag
University of Florida, Gainesville, FL
Erscheinungsjahr
2000
Zustand
Very good
Einband
Velobound
Auflage
1. Auflage

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