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Sprache: Englisch
Verlag: Springer Berlin Heidelberg, 2013
ISBN 10: 3662150476 ISBN 13: 9783662150474
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Buch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - Ironsands are a type of abundant, easily mined, and cost-effective coastal sand ore. This book explores various aspects of ironsands, including their mineral properties, milling, magnetic separation, and pre-oxidation treatments. It also examines the impact of ironsands on the sintering and pelletizing processes, as well as their influence on the quality of sinter and pelletized ore. Additionally, the book addresses the application of ironsands in gas-based direct reduction processes and high-temperature melting and splitting operations. The process of extracting titanium ferro-alloys from titanium-containing slag via the alumino-thermal method is also discussed. The book provides a comprehensive analysis of the intrinsic mechanisms involved in the extraction of valuable elements from ironsands, the impact of these processes on product quality, and offers recommendations for optimizing smelting techniques. Finally, it includes a specific case study on the short-flow industrial testing of ironsands.
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Taschenbuch. Zustand: Neu. Contemporary Metal Boron Chemistry I | Borylenes, Boryls, Borane Sigma-Complexes, and Borohydrides | Todd B. Marder (u. a.) | Taschenbuch | Structure and Bonding | xiv | Englisch | 2010 | Springer | EAN 9783642097393 | Verantwortliche Person für die EU: Springer Verlag GmbH, Tiergartenstr. 17, 69121 Heidelberg, juergen[dot]hartmann[at]springer[dot]com | Anbieter: preigu.
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Taschenbuch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - The eld of metal boron chemistry has been an especially active one since the 1960s. Much of the early work centered on the synthesis and structural characterization of polyhedral metallaborane and metallacarborane clusters, which will not be discussed in the current Volume. However, early work on metal boryl complexes by Nöth et al. also appeared during this period, - thoughthe rstsimple metalborylcomplexestobestructurallycharacterized bysingle-crystalX-raydiffractionwerenotreporteduntil1990(indeed,crystal structuresofiridiumhydridoborylcomplexeswerereportednearlysimulta- ouslybyBaker,Marder,etal. [1]andbyMerolaetal. [2]),andthisnewinterest in the area arose speci cally as a result of the report by Nöth et al. [3] on the rhodium-catalyzed hydroborationof alkenes using catecholborane. Although there had been previous reports of metal-catalyzed hydroboration employing polyhedralboranesorcarboranesastheB Hsource[4], theseminal paper by Nöth et al. in 1985 [3] marked the beginning of interest by the organic ch- istry community in the application of this reaction in organic synthesis [5]. Whatensuedwasaveryrapidincreaseinthenumberofmetalborylcomplexes to be synthesized and structurally characterized, along with studies of their reactivity,in conjunctionwithan equally rapid growthinthedevelopment of catalytichydroborationchemistry[5]anditsasymmetricversion[5e]. Thiswas followedbyawidevarietyofotherborylationreactionscatalyzedbytr ansition metals including diborations, silylborations, stannylborations, and thiabo- tions of unsaturated organic substrates [6], borylations of , -unsaturated carbonyl compounds [7], borylations of C halide bonds [8], and most - cently, borylations of C H bonds in alkenes, arenes, heteroarenes, and even alkanes[9,10]. TheC halideandC Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki Miyaura cross-coupling reaction[11],whichisnowoneofthemainC Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsinwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane -complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one.
Anbieter: AHA-BUCH GmbH, Einbeck, Deutschland
Buch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - The eld of metal boron chemistry has been an especially active one since the 1960s. Much of the early work centered on the synthesis and structural characterization of polyhedral metallaborane and metallacarborane clusters, which will not be discussed in the current Volume. However, early work on metal boryl complexes by Nöth et al. also appeared during this period, - thoughthe rstsimple metalborylcomplexestobestructurallycharacterized bysingle-crystalX-raydiffractionwerenotreporteduntil1990(indeed,crystal structuresofiridiumhydridoborylcomplexeswerereportednearlysimulta- ouslybyBaker,Marder,etal. [1]andbyMerolaetal. [2]),andthisnewinterest in the area arose speci cally as a result of the report by Nöth et al. [3] on the rhodium-catalyzed hydroborationof alkenes using catecholborane. Although there had been previous reports of metal-catalyzed hydroboration employing polyhedralboranesorcarboranesastheB Hsource[4], theseminal paper by Nöth et al. in 1985 [3] marked the beginning of interest by the organic ch- istry community in the application of this reaction in organic synthesis [5]. Whatensuedwasaveryrapidincreaseinthenumberofmetalborylcomplexes to be synthesized and structurally characterized, along with studies of their reactivity,in conjunctionwithan equally rapid growthinthedevelopment of catalytichydroborationchemistry[5]anditsasymmetricversion[5e]. Thiswas followedbyawidevarietyofotherborylationreactionscatalyzedbytr ansition metals including diborations, silylborations, stannylborations, and thiabo- tions of unsaturated organic substrates [6], borylations of , -unsaturated carbonyl compounds [7], borylations of C halide bonds [8], and most - cently, borylations of C H bonds in alkenes, arenes, heteroarenes, and even alkanes[9,10]. TheC halideandC Hborylationchemistryhasbeendrivenby thedevelopment andbroadapplicationoftheSuzuki Miyaura cross-coupling reaction[11],whichisnowoneofthemainC Cbond-formingreactionsinthe arsenal of the organic chemist. Thus, the synthetic and structural chemistry ofmetalborylcomplexeshasgrownalongwithcatalyticapplicationsinwhich metal borylcomplexes are key intermediates. Likewise, the importance of metal borane -complexes as intermediates in many catalytic reactions has only recently been recognized [12], and thisarea is now a rapidly expanding one.
Sprache: Englisch
Verlag: Springer Berlin Heidelberg, 2008
ISBN 10: 3642097391 ISBN 13: 9783642097393
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