The understanding of the principles of ICP-MS and its application as an analytical technique is continually evolving and this book provides a unique snapshot of the current state-of-the-art. Plasma Source Mass Spectrometry: The New Millennium covers a diverse range of topics including the fate of the sample as it passes through the sample introduction system, chemical resolution using reaction and collision cells, various methods of mass analysis, approaches to account for spectral interferences, hyphenation methods to enable speciation, and the results of analyses ranging from natural waters and archaeological isotope ratios to organometallic speciation in biological materials. Describing explicitly the analytical methods that deal with current analytical challenges, and offering a current perspective on elemental analysis by plasma source mass spectrometry that is not to be found elsewhere, this book will be welcomed by both academics and industrialists as containing the most up-to-date information available on this burgeoning topic.

Auszug. � Genehmigter Nachdruck. Alle Rechte vorbehalten.

Plasma Source Mass Spectrometry The New Millennium

By Grenville Holland, Scott D. Tanner

The Royal Society of Chemistry

1. Sample Preparation and Introduction,
Sample Introduction, Plasma-Sample Interactions, Ion Transport and Ion–Molecule Reactions: Fundamental Understanding and Practical Improvements in ICP-MS John W. Olesik, Carl Hensman, Savelas Rabb and Deanna Rago, 3,
Microwave Digestion of Oils for Analysis of Platinum Group and Rare Earth Elements by ICP-MS S. J. Woodland, C. J. Ottley, D. G. Pearson and R. E. Swarbrick, 17,
USN-ICPMS: A Poor Man's High Resolution David J. Gray, Charles Le Blanc, Wilson Chan and Bernie Denis, 25,
The Characteristics of an Off-line Matrix Removal/Pre-concentration System which uses Controlled Pore Glass Iminodiacetate as a Reagent for Inductively Coupled Plasma Mass Spectrometry Ted McGowan and Noel Casey, 37,
Moving to the Next Level: Sample Introduction and Plasma Interface Design for Improved Performance in ICP-MS E. McCurdy, S. Wilbur, G. D. Woods and D. Potter, 45,
2. Mass Analyser Instrumentation,
QMF Operation with Quadrupole Excitation V. J. Baranov, N. V. Konenkov and S. D. Tanner, 63,
All the Ions all the Time: Dream or Reality? Gary M. Hieftje, Steven J. Ray, John P. Guzowski Jr., Andrew M. Leach, Denis M. McLenathan, David A. Solyom, William C. Wetzel and Ole A. Gron, 73,
Evaluation of Inductively Coupled Plasma-Ion Trap Mass Spectrometry Naoki Furuta, Akihiro Takeda and Jian Zheng, 90,
3. Reaction Cells for ICP-MS,
Reaction Chemistry and Collisional Processes in Multipole Devices S. D. Tanner, V. I. Baranov and D. R. Bandura, 99,
Ion-Molecule Reactions in Plasma Source Mass Spectrometry Gregory K. Koyanagi and Diethard K. Bohme, 117,
Ion-Molecule Chemistry Solutions to the ICP-MS Analytical Challenges D. R. Bandura, S. D. Tanner, V. I. Baranov, G. K. Koyanagi, V. V. Lavrov and D. K. Bohme, 130,
A Reaction Mechanism for Solving the Oxide Problem in ICP-MS Analysis of the Noble Metals Lorna A. Simpson, Maryanne Thomsen and Brian J. Alloway, 148,
4. Applications,
Application and Quality of ICP-MS Analysis Thomas Prohaska, Gerhard Stingeder, Simon N. Nelms, Christophe Quetel, Christopher Latkoczy, Stephen Hann, Gunda Kollensperger and Philip D. P. Taylor, 165,
Trace Elements in Honey Samples by means of ETV-ICP-MS M. Bettinelli, S. Spezia, N. Pastorelli and C. Terni, 177,
Determination of Trace Elements in Ice Core Samples by Laser Ablation Inductively Coupled Plasma Mass Spectrometry H. Reinhard, M. Kriews, O. Schrems, C. Ludke, E. Hoffman and J. Skole, 185,
Rare Earth Element Concentrations for the Mobile-Alabama River Systems E. Y. Graham, W B. Lyons, K. A. Welch, T. Jones and J. C. Bonzongo, 195,
Application of ICP-MS to a Trace Elements Mass Balance Study in a Power Plant M. Bettinelli, S. Spezia, A. Fiore, W. Pastorelli and C. Terni, 208,
Determination of Mercury, Arsenic, Selenium and Antimony in Potable Water by ICP-MS J. Allibone, E. Fatemian and P. J. Walker, 216,
Determination of Metals in Sewage and Industrial Waste Waters by ICP-MS in a Single Run E. Fatemian, J. Allibone and P. J. Walker, 230,
5. Isotope Ratio Measurement,
The Performance of Commercial Mono-Elemental Solutions for High Accuracy Mass Spectrometry P. Evans, B. Fairman, C. Wolf-Briche, S. Merson and C. Harrington, 245,
ICP-MS Applied to Isotope Abundance Ratio Measurements: Performance Study and Development of a Method for Combining Uncertainty Contributions from Measurement Correction Factors Christophe R. Quetel, Thomas Prohaska, Simon M. Nelms, Jurgen Diemer and Philip D. P. Taylor, 257,
Comparison of MC-ICP-MS with Quadrupole ICP-MS for the Certification of the Amount, Content and Isotopic Composition of Enriched 206Pb and 203Tl Materials Using Isotope Dilution Simon M. Nelms, Thomas Prohaska, Christophe R. Quetel and Philip D. P. Taylor, 270,
Which Way for Os? A Comparison of Plasma-Source Versus Negative Thermal Ionisation Mass Spectrometry for Os Isotope Measurement D. G. Pearson and C. J. Ottley, 279,
Matrix-induced Isotopic Mass Fractionation in the ICP-MS Richard W. Carlson, Eric H. Hauri and Conel M. O'D. Alexander, 288,
Simultaneous Acquisition of Isotope Compositions and Parent/Daughter Ratios by Non-isotope Dilution-mode Plasma Ionisation Multi-collector Mass Spectrometry (PIMMS) G. Nowell and R. R. Parrish, 298,
Combined Pb-, Sr- and O-Isotope Analysis of Human Dental Tissue for the Reconstruction of Archaeological Residential Mobility P. Budd, J. Montgomery, J. Evans and C. Chenery, 311,
6. Speciation,
Isotope Dilution Analysis for Trace Metal Speciation J. Ignacio Gracia Alonso, Jorge Ruiz Encinar, Cristina Sariego Muniz, J. Manuel Marchante Gayon and Alfredo Sanz Medel, 327,
Prediction of Inorganic Aqueous Speciation: A Useful Tool for ICP-MS and IC-ICP-MS Analysts D. A. Polya and P. R. Lythgoe, 347,
Investigations into Biovolatilisation of Metal(loids) in the Environment by using GC-ICP-TOF-MS Jorg Feldmann, Karsten Haas, Laurent Naels and Silvia Wehmeier, 361,
Time-of-Flight Inductively Coupled Plasma Mass Spectrometry for Ultratrace Speciation Analysis of Organometallic Compunds Heidi Goenaga Infante, Monika Heisterkamp, Karen Van Campenhout, Xiaodan Tian, Ronny Blust and Freddy C. Adams, 369,
An Appetite for Arsenic The Seaweed Eating Sheep from Orkney Jorg Feldmann, Thorsten Balgert, Helle Hansen and Paramee Pengprecha, 380,
Hyphenated IC-ICP-MS for the Determination of Arsenic Speciation in Acid Mine Drainage A. G. Gault, D. A. Polya and R. R. Lythgoe, 387,
Selenium Speciation in Human Urine B. Gammelgaard, L. Bendahl and O. Jons, 401,
Sensitive Detection of Platinum-Bound DNA Using ICP-MS and Comparison to Graphite Furnace Atomic Absorption Spectroscopy (GFAAS) A. Azim-Araghi, C. J. Ottley, D. G. Pearson and M. J. Tilby, 412,
Author Index, 419,
Subject Index, 422,

CHAPTER 1

Section 1

Sample Preparation and Introduction

SAMPLE INTRODUCTION, PLASMA-SAMPLE INTERACTIONS, ION TRANSPORT AND ION-MOLECULE REACTIONS: FUNDAMENTAL UNDERSTANDING AND PRACTICAL IMPROVEMENTS IN ICP-MS

John W. Olesik, Carl Hensman, Savelas Rabb and Deanna Rago

Laboratory for Plasma Spectrochemistry, Laser Spectroscopy and Mass Spectrometry, Department of Geological Sciences, Ohio State University, Columbus, OH 43210, USA

1 INTRODUCTION

Improved fundamental understanding of the processes that control ICP-MS signals can lead to practical improvements in analytical capabilities. Here we discuss high efficiency analyte transport at sample uptake rates as high as 0.8 mL/min and the unique behavior of selenium which when present at high concentrations is vaporized before other elements. We also explore the use of ion-molecule reactions in a dynamic reaction cell to overcome spectral overlaps and examine the ability of the quadrupole-based cell to prevent formation of undesired product ions.

Droplet-droplet collisions and coagulation in the spray chamber appear to be the main processes that limit analyte transport efficiency. When the sample uptake rate is increased, transport efficiency naturally decreases. By promoting evaporation within the spray chamber, it is possible to attain virtually 100% sample transport efficiency. The deleterious effects of solvent vapor loading prevent use of high analyte transport rates unless...

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