Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance (BestMasters) - Softcover

Buch 32 von 91: BestMasters

Soetbeer, Janne Marie

 
9783658146696: Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance (BestMasters)
Softcover
ISBN 10: 3658146699 ISBN 13: 9783658146696
Verlag: Springer Spektrum, 2016

Inhaltsangabe

Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. 

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Über die Autorin bzw. den Autor

Janne Marie Soetbeer completed her Master’s Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke’s group.

Von der hinteren Coverseite

Janne Marie Soetbeer determines the optimal dynamical decoupling (DD) scheme for efficient reduction of electron spin coherence loss in model systems for spin labelled biomolecules depending on their particular relaxation behavior. Extending the nth order DD scheme to double electron-electron resonance (DEER) experiments require the addition of multiple pump pulses for ≠ 1. Incomplete excitation of pump spin packets introduce signal artefacts which are minimized by pump pulse optimization including linear-chirp and asymmetric hyperbolic secant pulses. Prolonging the dipolar evolution time with decreased signal artefact allows to extent the measurable interspin distances in biomolecules which were otherwise not accessible due to spin echo relaxation. 

Contents
  • The Spin Hamiltonian
  • Pulsed EPR Experiments
  • Relaxation Processes
  • Dynamical Decoupling
  • Model Systems
Target Groups
Lecturers and Students of Chemistry, especially of Physical Chemistry

The Author
Janne Marie Soetbeer completed her Master’s Thesis at the Swiss Federal Institute of Technology in Zurich, Switzerland. After a research stay with Prof. Dr. Robert Griffin at the Massachusetts Institute of Technology in Cambridge, USA, she will be returning to Zurich to start her PhD in Prof. Dr. Gunnar Jeschke’s group.

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Verlag
Springer Spektrum
Erscheinungsdatum
2016
Sprache
Englisch
ISBN 10 
3658146699
ISBN 13 
9783658146696
Einband
Taschenbuch
Auflage
1
Anzahl der Seiten
96
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Weitere beliebte Ausgaben desselben Titels

9783658146719: Dynamical Decoupling in Distance Measurements by Double Electron-Electron Resonance

Vorgestellte Ausgabe

ISBN 10:  3658146710 ISBN 13:  9783658146719
Verlag: Springer Spektrum, 2016
Softcover