High Energy Density Materials (Structure and Bonding, Band 125) - Softcover

9783642091353: High Energy Density Materials (Structure and Bonding, Band 125)

Softcover

ISBN 10: 3642091350 ISBN 13: 9783642091353

Verlag: Springer, 2010

FOX-7 (1,1-Diamino-2,2-dinitroethene).- Nitrogen-Rich Heterocycles.- New Nitrogen-Rich High Explosives.- Organic Difluoramine Derivatives.- Computational Aspects of Nitrogen-Rich HEDMs.- Sensitivities of High Energy Compounds.

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Verlag: Springer
Erscheinungsdatum: 2010
Sprache: Englisch
ISBN 10: 3642091350
ISBN 13: 9783642091353
Einband: Taschenbuch
Anzahl der Seiten: 300
Herausgeber: Klap�tke Thomas M.
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High Energy Density Materials

Thomas M. Klap�tke

Verlag: Springer, 2010

ISBN 10: 3642091350 ISBN 13: 9783642091353

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High Energy Density Materials

Thomas M. Klap�tke

Verlag: Springer, 2010

ISBN 10: 3642091350 ISBN 13: 9783642091353

Neu Taschenbuch

Anbieter: AHA-BUCH GmbH, Einbeck, Deutschland

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Taschenbuch. Zustand: Neu. Druck auf Anfrage Neuware - Printed after ordering - This book summarizes some recent developments in the area of high-energy high-density (HEDM) materials. Rather than being comprehensive in scope, emphasis is given to structural and bonding features of highly energetic - terials with possible applications as high explosives (secondary explosives) or propellants. In this book we do not focus on primary explosives (e.g. lead azidereplacements)sincebyde nitiontheexplosiveperformance(detonation velocity and detonation pressure) of such materials although very sensitive are much less energetic than secondary (high) explosives. Modern HEDMs derive most of their energy (i) from oxidation of the c- bon backbone, as in traditional energetic materials, (ii) from ring or cage strain, or (iii) from their very high positive heat of formation. Examples of the rstclassare traditionalexplosives, suchasTNT,RDXand HMX.Modern nitro-compounds, such as CL-20 or the recently reported hepta- and octa- trocubanes, belong to the second group of explosives and possess very high densities and enhance the energies utilizing substantial cage strain. Members of the third class of compounds are high-nitrogen compounds (up to 85% - trogencontent), such as aminotetrazole and nitrotetrazolederivatives, which show the desired remarkable insensitivity to electrostatic discharge, friction and impact, while having very high positive heats of formation and therefore very high explosive powers. The synthesis of energetic, non-nuclear materials for military application has been a long-term goal in various academic and military research groups worldwide. Some of the current challenges that face HEDMscientists are: Demandforenvironmentallycompatibleandtoxicologicallyacceptable- plosives and propellants. Examples are replacements for TNT, RDX and HMXsince nitro-explosivesper se,aswellastheir environmental transf- mation products, are toxic. Artikel-Nr. 9783642091353

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