The combination of its unique morphology, physical properties, cost effectiveness and environmental friendliness make natural rubber an appealing constituent for many materials and applications. This comprehensive two volume set covers the synthesis, characterization and applications of natural rubber based blends, interpenetrating polymer networks, composites and nanocomposites.
Volume 1 covers different types of natural rubber-based blends and IPNs as well as manufacturing methods, thermo mechanical characterization techniques, life cycle analysis and their applications. Volume 2 focuses on natural rubber-based composites and Nanocomposites including the different types of fillers, the filler-matrix reinforcement mechanisms, manufacturing techniques, and applications.
This is the first book to consolidate the current state of the art information on natural rubber based materials with contributions from established international experts in the field. The book provides a "one stop" reference resource for professionals, researchers, industrial practitioners, graduate students, and senior undergraduates in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering.
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Sabu Thomas is professor at the School of Chemical Sciences, Mahatma Gandhi University, Kottayam, India. He received Ph.D from Indian Institute of Technology, Kharagpur and a B.Tech in Polymer Science and Technology from Cochin University. Prof. Thomas has gained additional experience as a visiting professor at a number of universities around the world. A Fellow of the Royal Society of Chemistry and a member of the American Chemical Society, his research has led to the publication of some 360 articles in international peer reviewed journals, several book chapters and patents. The co-editor of four books, he has been a visiting professor and lecturer at some of the world's leading polymer research laboratories.
The combination of its unique morphology, physical properties, cost effectiveness and environmental friendliness make natural rubber an appealing constituent for many materials and applications. This comprehensive two volume set covers the synthesis, characterization and applications of natural rubber based blends, interpenetrating polymer networks, composites and nanocomposites.
Volume 1 covers different types of natural rubber-based blends and IPNs as well as manufacturing methods, thermo mechanical characterization techniques, life cycle analysis and their applications. Volume 2 focuses on natural rubber-based composites and Nanocomposites including the different types of fillers, the filler-matrix reinforcement mechanisms, manufacturing techniques, and applications.
This is the first book to consolidate the current state of the art information on natural rubber based materials with contributions from established international experts in the field. The book provides a "one stop" reference resource for professionals, researchers, industrial practitioners, graduate students, and senior undergraduates in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering.
Chapter 1 Natural Rubber Based Blends and IPNs: State of the Art, New Challenges and Opportunities Gordana Markovic, Milena Marinovic-Cincovic, Vojislav Jovanovic, Suzana Samarzija-Jovanovic and Jaroslava Budinski-Simendic, 1,
Chapter 2 Natural Rubber: Biosynthesis, Structure, Properties and Application Jitladda Tangpakdee Sakdapipanich and Porntip Rojruthai, 28,
Chapter 3 Non-Rubbers and Abnormal Groups in Natural Rubber Eng Aik Hwee, 53,
Chapter 4 The Production of Natural Rubber from Hevea brasiliensis Latex: Colloidal Properties, Preservation, Purification and Processing C. C. Ho, 73,
Chapter 5 Natural Rubber Blends and Based IPNs: Manufacturing Methods Wanvimon Arayapranee, 107,
Chapter 6 Filler Migration in Natural Rubber Blends During the Mixing Process Hai Hong Le, Sybill Ilisch, Gert Heinrich and Hans-Joachim Radusch, 132,
Chapter 7 NR Blends and IPNs: Miscibility and Immiscibility Wiwat Pichayakorn, Jirapornchai Suksaeree and Prapaporn Boonme, 177,
Chapter 8 Natural Rubber Based Non-Polar Synthetic Rubber Blends Seiichi Kawahara, 195,
Chapter 9 Natural Rubber Based Polar Synthetic Rubber Blends Konstantinos G. Gatos, 213,
Chapter 10 Thermoplastic Elastomers from High-Density Polyethylene/Natural Rubber/Thermoplastic Tapioca Starch: Effects of Different Dynamic Vulcanization Mohd Kahar Ab Wahab, Nadras Othman and Hanafi Ismail, 242,
Chapter 11 Natural Rubber/Engineering Thermoplastic Elastomer Blends E. Purushothaman and Mehar Al Minath, 265,
Chapter 12 Radiation Processing of Natural Rubber with Vinyl Plastics Chantara Thevy Ratnam, Zurina Mohamad and Mohammad Khalid Siddiqui, 284,
Chapter 13 Blends and IPNs of Natural Rubber with Acrylic Plastics Wiwat Pichayakorn, Jirapornchai Suksaeree and Prapaporn Boonme, 300,
Chapter 14 Photoreactive Nanomatrix Structures Formed by Graft Copolymerization of 1,9-Nonanediol Dimethacrylate onto Natural Rubber Oraphin Chaikumpollert, Nanthaporn Pukkate and Seiichi Kawahara, 324,
Chapter 15 Blends and IPNs of Natural Rubber with Thermosetting Polymers Raju Thomas, Ishak Ahmad, Sahrim Hj. Ahmad and Shinu Koshy, 336,
Chapter 16 Natural Rubber Blends with Biopolymers Silvia Maria Martelli, Carol Sze Ki Lin, Zheng Sun, Nathalie Berezina, Farayde Matta Fakhouri and Lucia Helena Innocentini-Mei, 349,
Chapter 17 Clay Reinforcement in Natural Rubber Based Blends: Micro and Nano Length Scales Yamuna Munusamy, Hanafi Ismail and Chantara Thevy Ratnam, 370,
Chapter 18 Rheological Behaviour of Natural Rubber Based Blends Ploenpit Boochathum, 394,
Chapter 19 Spectroscopy: Natural Rubber Based Blends and IPNs SA-AD Riyajan, 441,
Chapter 20 Mechanical and Viscoelastic Properties of Natural Rubber Based Blends and IPNs Wiwat Pichayakorn, Jirapornchai Suksaeree and Prapaporn Boonme, 481,
Chapter 21 Scattering Studies on Natural Rubber Based Blends and IPNs Valerio Causin, 501,
Chapter 22 Transport of Penetrant Molecules Through Natural Rubber Based Blends and IPNs Isaac O. Igwe, 530,
Chapter 23 Life Cycle Analysis, Ageing and Degradation Behaviour of Natural Rubber Based Blends and IPNs Cristina Russi Guimarães Furtado and Márcia Christina Amorim Moreira Leite, 550,
Chapter 24 Application of Natural Rubber Based Blends and IPNs in Tyre Engineering and other Fields Mir Hamid Reza Ghoreishy and Mohammad Alimardani, 569,
Subject Index, 600,
Natural Rubber Based Blends and IPNs: State of the Art, New Challenges and Opportunities
GORDANA MARKOVIC, MILENA MARINOVIC-CINCOVIC, VOJISLAV JOVANOVIC, SUZANA SAMARZIJA-JOVANOVIC AND JAROSLAVA BUDINSKI-SIMENDIC
1.1 Introduction and History
The field of polymer science and technology has undergone an enormous expansion over recent decades primarily as a result of chemical diversity. Dilute solution behaviour, elasticity, tacticity, single crystal formation, viscoelastic behaviour, etc., attained the prime interest from past researchers. The concept of physically blending two or more existing polymers to obtain new products is now attracting widespread interest and commercial utilization.
Investigation of polymer blends is one of the most active areas of research and development in the field of polymers at the present time. Polymer blends provide answers to technological challenges posed by the increasing difficulties of synthesizing new monomers and polymers to meet diverse demands, either domestic or industrial. The wide range of properties attainable with these systems were hitherto either impossible to obtain from an individual polymer or would involve costly development of new polymers. In fact, blending of polymers is one of the easiest and most flexible methods of generating new polymeric materials. It has become an important technique for improving the cost–performance ratio of commercial polymers. Polymer blends also provide a platform for scientific investigations in various fields such as newer characterization techniques, processing, molecular engineering to control the blend structure, structure-property correlation and modelling, etc.
It is important to be able to predict and understand the resultant properties of a blend and its morphology from the properties of the constituent polymers. Predicting the mechanical behaviour of polymer blends and composites with respect to composition, structure (morphology of the blend) and properties of the components covering a wide temperature range are particularly important.
Polymer blends and interpenetrating polymer networks (IPNs) form part of the composite materials system. Composite materials may be defined as materials made up of two or more phases. They may be grouped into:
(i) particulate filled: consisting of a continuous matrix phase and a discontinuous filler phase made up of discrete particles;
(ii) fibre filled;
(iii) skeletal IPNs: both as continuous phases.
The factors that influence the properties of composite materials are: properties of the components, shape of the filler phase, morphology of the system, and the nature of the interface between the phases. The mechanical behaviour of composites is greatly affected by the interfacial adhesive bond between the phases. The morphology in polymer blends is indicative of the phase or phases and interrelationships existing in the blend. It reflects the domain size of the dispersed phase, state of aggregation, nature of the interface between the phases, etc. phase is nothing but a structurally homogeneous part of a material system. There may be a single continuous phase with one or more disperse phases, or two or more continuous phases which may contain one or more disperse phases. Blends are defined as simply a mixture of two or more polymers or copolymers. They may be miscible (domain size of the order of 0.5 nm) or immiscible (domain size of the order of 100 nm), depending on thermodynamic requirements. Miscible blends are thermodynamically stable, molecular level mixtures. Immiscible blends are separated into microscopic phases with very minimum interfacial adhesion and unstable morphology. Polymer alloy blends (PABs) are a class of polymer blends, heterogeneous in nature, with controlled morphology and properties, achieved by...
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