This reference book describes how bioprocessing and biotechnology could enhance the value extracted from wood-based lignocellulosic fiber by employing both biochemical and thermochemical conversion processes. It documents recent accomplishments and suggests future prospects for research and development of integrated forest biorefineries (IFBR) as the path forward for the pulp, paper and other fiber-processing industries. This is the only book to cover this area of high economic, social, and environmental importance. It is aimed at industrialists and academics from diverse science and engineering backgrounds including chemical and biotechnology companies, governmental and professional bodies, and scholarly societies. The Editor and contributors are internationally recognized scientists and many are leaders in their respective fields. The book starts with an introductory overview of the current state of biorefining and a justification for future developments. The next four chapters deal with social, economic and environmental issues related to regulations, biomass production and supply, process modelling, and life cycle analysis. Subsequent chapters focus on the extraction of biochemicals from biomass and their potential utilization to add value to the IFBR prior to pulping. The book then presents, compares and evaluates two types of forest biorefineries based on kraft and organosolv pulping. Finally, the book assess the potential of waste biomass and streams, such paper mill sludge and black liquor, to serve as feedstock for biofuel production and value-added biomaterials through both the biochemical and thermochemical routes of biomass bioprocessing. The economics of the described IFBR processes and products, and their environmental impact, is a major focus in most of the chapters. Practical examples are presented where relevant and applicable.
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Professor Lew P. Christopher has twenty years experience in wood science, the pulp and paper industry, biotechnology, and bioprocessing. His research output exceeds 230 scientific contributions including peer-reviewed papers, book chapters, technical reports, invited lectures, and conference presentations. He is also the inventor of several international patents. For eleven years, Professor Christopher worked in research and development at Sappi, a large international pulp and paper company. He was also Affiliate Professor at the University of the Free State and University of Pretoria in South Africa. Now Director of the Center for Bioprocessing Research and Development at the South Dakota School of Mines and Technology, Professor Christopher leads a large team developing technologies for production of biomass-derived biofuels and value-added bioproducts. He is also on the Editorial Board of several international journals and is an active member of a number of professional societies. He has chaired sessions at various international biotechnology conferences and, in 2004, organized the 9th International Conference on Biotechnology in the Pulp and Paper Industry. Dr Christopher is currently serving on the National Science Foundation Industrial Advisory Board of the Industry-University Cooperative Research Center on BioEnergy R&D and on the International Scientific Advisory Committee on Renewable Resources and Biorefineries.
Integrated Forest Biorefineries: Challenges and Opportunities describes how bioprocessing and biotechnology could enhance the value extracted from wood-based lignocellulosic fiber by employing both biochemical and thermochemical conversion processes. It documents recent accomplishments and suggests future prospects for research and development of integrated forest biorefineries (IFBR) as the path forward for the pulp, paper and other fiber-processing industries. This is the only book to cover this area of high economic, social, and environmental importance. It is aimed at industrialists and academics from diverse science and engineering backgrounds including chemical and biotechnology companies, governmental and professional bodies, and scholarly societies. The Editor and contributors are internationally recognized scientists and many are leaders in their respective fields. The book starts with an introductory overview of the current state of forest biorefining, technological challenges and perspectives for future developments. The next three chapters deal with economic, environmental and sustainability issues related to policy regulations, biomass production, supply chains, product development and market conditions for the forest products industry. The subsequent four chapters focus on the selective removal of hemicellulose, lignin and extractives from woody biomass and their potential utilization through economic modeling and process integration to obtain biofuels and value-added bioproducts. The last three chapters review the latest developments in utilization of woody biomass for production of hydrocarbon fuels through gasification and pyrolysis; biohydrogen by anaerobic dark fermentation; and bio-based composite materials. The economics of the described IFBR processes and products, and their environmental impact, is a major focus in most of the chapters. Practical examples are presented where relevant and applicable.
List of Abbreviations, xxi,
Chapter 1 Introduction, 1,
Chapter 2 Vegetable Oil as a Fuel: Can it be used Directly?, 5,
Chapter 3 Biodiesel Properties and Specifications, 31,
Chapter 4 Oxidation Stability of Biodiesel, 51,
Chapter 5 Low-Temperature Flow Properties of Biodiesel, 80,
Chapter 6 Dependence of Other Properties of Biodiesel on Fatty Acid Methyl Ester Composition and Other Factors, 107,
Chapter 7 Major Resources for Biodiesel Production, 168,
Chapter 8 Diesel Engine Efficiency and Emissions using Biodiesel and its Blends, 140,
Chapter 9 Present State and Policies of the Biodiesel Industry, 204,
Chapter 10 The Food Versus Fuel Issue: Possible Solutions, 231,
Subject Index, 239,
Integrated Forest Biorefineries: Current State and Development Potential
LEW P. CHRISTOPHER
Center for Bioprocessing Research and Development and Department of Civil and Environmental Engineering, South Dakota School of Mines and Technology, Rapid City 57701, South Dakota, USA
Email: lew.christopher@sdsmt.edu; Tel.: + 1-605-394-3385
1.1 Introduction
The motivation for development and use of biofuels is currently driven by several important factors: 1) diminishing reserves of readily recoverable oil; 2) increasing demand and prices of petroleum-derived fuel; 3) concerns over increasing greenhouse gas emissions and global climate change; 4) growing food needs; and 5) desire for energy independence and security. The total energy world consumption in 2005 was 488 EJ with U.S. consumption of 22% of the world total, which is expected to surpass 650 EJ by 2025 and grow approximately 40% over the next 25 years. Future oil supply is not unlimited or assured as currently available petroleum fuel reserves are estimated to become nearly depleted within 40 years. Crude oil prices have risen from less than $20/ barrel in the 1990s to nearly $100/barrel in 2007 with a current annual volatility of crude oil prices exceeding 30%. Government-controlled national oil companies and organizations, many in countries that are unstable or prone to conflict, command and control more than 75% of the world's known oil reserves and global oil production. The U.S. imports 10 million barrels of oil per day of the existing oil reserves of 1.3 trillion barrels.
In 2004, fossil fuels accounted for 86% of the U.S. total energy consumption, with an additional 8% from nuclear power and only 6% from renewable sources, including 3% of biomass-derived biofuels. Biomass, however, is the single renewable resource on earth, reproduced at 60 billion tons per year (as organically-bound carbon), that has the potential to supplant the use of liquid transportation fuels and help create a more stable energy future. In general, around 30% of the world's primary energy is derived from biomass with around 430 g carbon produced per square meter of land per year. The U.S. and other regions of the world have abundant biomass resources which are much more evenly distributed and accessible throughout the planet than the oil reserves. In their "billion ton vision", the U.S. Department of Energy (DOE) reported that nearly 1.3 billion dry tons of biomass could become available to produce biofuels and displace more than 30% of the nation's consumption of liquid transportation fuels. However, the biomass share of the U.S. energy supply in 2004 was less than 3% of the total, compared to 40% and 23%, derived from petroleum and coal, respectively. Although biomass ranks well below petroleum, natural gas, and coal and is about one-half of nuclear, it surpasses hydroelectric and other renewable sources, and in 2009, the share of biomass in the total U.S. energy consumption exceeded 4% for the first time.
While ethanol production from corn and sugarcane (first generation biofuels) is a well-established process, cellulosic ethanol (second generation biofuels) is yet to be commercialized. The DOE Roadmap envisages large-scale production of second generation biofuels to become a nation-wide reality beyond 2020. The cellulosic biomass base is composed of a wide variety of forestry and agricultural resources that include forest thinning, wood mill residues, logging residues, paper waste, tree trimmings, grass clippings, energy crops such as switchgrass and miscanthus, sugarcane waste (bagasse), wheat straw, rice straw, corn stover and corn cobs.
According to the "billion ton vision" of DOE, two-thirds of the biomass resources in the U.S. represent agricultural waste, whereas about a third is forest-based. Forests cover 30% of the earth (about 3.9 billion hectares) and play a major role in preservation of biodiversity, soil conservation, and prevention of climate change serving as a major carbon dioxide sink. The forest resources are sustainable and provide long-term economic benefits to more than 1.6 billion people with a market of forest products estimated at $327 billion per year. Wood is used to produce heat for domestic and industrial purposes, and due to its strength properties, it is the primary construction material in more than 145 countries around the world. Wood is also used as a chemical feedstock to produce charcoal, tar, pitch, pulp fibers, paper, etc. Therefore, the wood-based value chain includes wood products, paper products, energy, and wood-derived chemicals. Due to the wood's increasing use and demand, approximately 130 000 km2 of forest are lost as deforestation every year. In addition, large areas of forest lands are littered with an unnatural accumulation of stunted, overcrowded trees and woody debris. Decades of fire suppression have disrupted the natural fire cycle of U.S. forests. Fires on these overstocked stands are more intense and harder to control than forest fires in previous decades, and they often result in catastrophic crown fires that kill large areas of forestlands. An estimated 8.4 billion dry tons of material needs to be removed from the national forests to reduce the risk of fire hazard, insect infestation, and disease. This vast source of biomass is available for production of wood products, chemicals, and energy. The biomass-derived energy use is projected to grow 35% from 2010 to 2024.
To combat the above processes, sustainable forest management practices need to include activities such as forest carbon credits, afforestation, reforestation, and the active support of government, forest companies and landowners. Government policies, carbon credits and carbon markets can be used as a tool to offset greenhouse gas (GHG) emissions. "Carbon credit" is a generic term for any tradable certificate or permit representing the right to emit one ton of carbon dioxide or the mass of another greenhouse gas with a carbon dioxide equivalent to one ton of carbon dioxide. Since GHG mitigation projects generate credits, this approach can be used to finance carbon reduction schemes between trading partners and around the world though carbon markets. Plant-derived biofuels as a carbon-neutral technology have to achieve at least 60% lower emissions than petroleum fuel based on lifecycle studies that include all emissions resulting from making the fuel from the field to the tank. Meeting these goals will require significant and rapid advances in biomass feedstock and conversion technologies; availability of large volumes of sustainable biomass feedstock; demonstration and deployment of large scale, integrated...
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