Adsorption and the Gibbs Surface Excess - Softcover

Inhaltsangabe

1: Introduction.- 1.1. Adsorption from Solution.- 1.2. Nature of the Interface.- 1.3. Nature of the Adsorbate.- 1.4. Nature of the Bulk Phase.- 1.5. Thermodynamics of the Bulk Phase.- 1.6. Partial Molal Quantities.- 1.7. Gas or Vapor Phase.- 1.8. Binary Solution of a Liquid.- 1.9. Activity Coefficient of an Electrolyte.- 1.10. Standard Free Energy Change of a Chemical Reaction.- 1.11. Solute Distribution between Two Insoluble Liquid Phases.- 1.12. The Surface Energy.- 1.13. Surface Tension and Mechanical Equilibrium.- 1.14. Surface Free Energy.- 2: Experimental Methods and Procedures.- 2.1. Introduction.- 2.2. Measurement of Boundary Tension.- 2.3. Surface Pressure of Insoluble Film.- 2.4. Equilibrium Spreading Pressure.- 2.5. Measurement of Contact Angle.- 2.6. Adsorption by Powdered Solid from Binary Solution.- 2.7. Direct Analysis of Adsorption at the Liquid Interface.- 2.8. Water Vapor Adsorption by Biopolymers.- 2.9. Detergent-Biopolymer Binding from Equilibrium Dialysis.- 3: Adsorption at Liquid Interfaces and the Gibbs Equation.- 3.1. Introduction.- 3.2. Adsorption at Liquid Interfaces.- 3.3. The Interfacial Phase.- 3.4. Physical Model for the Surface Phase.- 3.5. The Bulk Phases.- 3.6. The Gibbs Adsorption Equation.- 3.7. Relative Surfaces Excesses.- 3.8. Total Concentration and Surface Excess.- 3.9. Adsorption and Surface Excess.- 3.10. Absolute Composition of the Interfacial Phase.- 3.11. Binary Mixture of Liquids.- 3.12. Monolayer Model.- 3.13. Boundary Tension of Solutions of Inorganic Electrolytes.- 3.14. Negative Adsorption of an Electrolyte.- 3.15. Discussion on the Derivation of the Gibbs Equation.- 3.16. Alternative Treatment for the Adsorption Equation.- 3.17. Surface Activity Coefficients.- 3.18. Summary and Comments.- 4: Adsorption at the Liquid Interface from the Multicomponent Solution.- 4.1. Introduction.- 4.2. Surface Excess for Multicomponent Solutions.- 4.3. Gibbs Equation for the Mixture of Nonelectrolytes.- 4.4. Solution of Organic Electrolytes and the Electrical Double Layer.- 4.5. Electroneutrality in the Interfacial Phase.- 4.6. Gibbs Equation for Electrolyte Adsorption.- 4.7. The Helmholtz Double Layer.- 4.8. Helmholtz Model and the Gibbs Adsorption Equation.- 4.9. Gouy-Chapman Double Layer.- 4.10. Gouy Model and the Gibbs Adsorption Equation.- 4.11. Debye-Hückel Theory and the Gibbs Adsorption Equation.- 4.12. Experimental Values of the Coefficient m.- 4.13. Stern Model of the Double Layer.- 4.14. Gibbs Equations for More Than Two Electrolyte Components.- 4.15. Gibbs Equations for Miscellaneous Types of Experimental Procedures.- 4.16. Surface Excesses for Small Cations and Anions.- 4.17. Coadsorption of Organic Ions.- 4.18. Summary and Comments.- 5: Adsorbed Monolayers and Energies of Adsorption.- 5.1. Introduction.- 5.2. Adsorbed and Spread Monolayers.- 5.3. Ideal Equation of State.- 5.4. Neutral Monolayers at the Oil-Water Interface.- 5.5. Surface Pressure and Osmotic Pressure.- 5.6. Binary Solution at the Interfacial Phase.- 5.7. Ionized Monolayers at the Oil-Water Interface.- 5.8. The Electrical Pressure and the Gouy Model.- 5.9. The Discrete-Ion Effect.- 5.10. Counterion Binding.- 5.11. Discussion on the Computation of ?e.- 5.12. Electrical Double Layer and Electrical Free Energy.- 5.13. Equation of State at the Air-Water Interface.- 5.14. Free Energies of Adsorption at the Liquid Interface.- 5.15. Generalized Form of the Surface Equation of State.- 5.16. Summary and Comments.- 6: Spread Monolayer.- 6.1. Introduction.- 6.2. States of Monomolecular Films.- 6.3. Equation of State for Monomolecular Films.- 6.4. Thermodynamics of Spread Monolayers.- 6.5. Surface Activity Coefficient.- 6.6. Protein and Polymer Films.- 6.7. Rigorous Equations of State for Polymer Films.- 6.8. Virial Equation of State for Two-Dimensional Polymer Films.- 6.9. Charged Monolayers of Amphiphiles and Biopolymers.- 6.10. Helmholtz Free Energy for Protein Monolayers.- 6.11. Analysis of Protein Unfolding at Interfaces.-

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