Intermediate and Complex Ions; V. The Solubility Product and Activity of the Ions in Bi-Bivalent Salt: A Dissertation Submitted to the Faculty of the ... of Doctor of Philosophy, Department of Chemi - Softcover

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Excerpt from Intermediate and Complex Ions; V. The Solubility Product and Activity of the Ions in Bi-Bivalent Salt: A Dissertation Submitted to the Faculty of the Ogden Graduate School of Science in Candidacy for the Degree of Doctor of Philosophy, Department of Chemistry

While the evidence for the existence of complex ions in solutions of bi-bivalent salts is neither so complete or so perfect as that obtained in solutions of uni-bivalent salts from the standpoint of the solubility re sults obtained thus far, there is an independent line of evidence which could not be obtained in the latter case; that is the mobility of the ions in bi-bivalent salt solutions decreases rapidly as the concentration of the solu tion increases. This change is in the direction to be expected if complex ions are present. Such complex ions differ from the complex ions usually considered in the literature in that the evidence points to their existence in dilute solutions, just as is the case with intermediate ions. In this re spect the complex ions considered in this paper are more like such inter mediate ions; and so might well be called intermediate ions, since they are intermediate between the single and the double molecules of the salt.

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