Although catalysts are responsible for the manufacture and processing of a number of products in daily use, the subject of catalysis is still very much in its infancy, and the complexity of the processes still present major challenges. Catalysis in Application presents a snapshot of the most up-to-date developments in the field of applied catalysis. Coverage is principally in the areas of hydrogenation, dehydrogenation, chiral catalysis, environmental catalysis and catalyst deactivation, combining a unique mix of chemistry and chemical engineering. With its wide-ranging coverage, this book will be a welcome addition to the shelves of every practitioner in catalysis, both in industry and academia.
Die Inhaltsangabe kann sich auf eine andere Ausgabe dieses Titels beziehen.
Modification of catalysis and surface reactions by surface carbon M. Bowker, T. Aslam, C. Morgan and N. Perkins, 1,
Catalytic properties of the platinum-hydrogen-carbon system Z. Paál and A. Wootsch, 8,
Deactivation kinetics of cobalt-nickel catalysts in a fluidised bed reformer K.M. Hardiman, M.M. Mohammed and A.A. Adesina, 16,
Deactivation behaviour of Zn/ZSM-5 with a Fischer-Tropsch derived feedstock A. de Klerk, 24,
In-situ ultraviolet Raman spectroscopy of supported chromidalumina catalysts for propane dehydrogenation V.S. Sullivan, P.C. Stair and S.D. Jackson, 32,
Butane dehydrogenation over a Walumina catalyst S.D. Jackson, D. Lennon and J.M. McNamara, 39,
Selective hydrogenation of cinnamaldehyde to cinnamyl alcohol using an Ir/C catalyst: influence of reaction conditions J.P. Breen, R. Burch, J. Gomez-Lopez, K. Grifin and M. Hayes, 45,
Study of catalyzed wall-flow and foam-type fine particulate filters A. G. Konstandopoulos, D. Zuwalis, J.M. McNamara, S. Poulston and R. R. Rajaram, 53,
A novel "thrifted" palladium-zinc catalyst supported on ceria stabilised zirconia for use in three way vehicle exhaust catalysis J. Thomson, P.C.J. Anstice and R.D. Price, 63,
Enantioselectivity and catalyst morphology G.A. Attard, D.J. Jenkins, O.A. Hazzazi, P.B. Wells, J.E. Gillies, K.G. Grifin and P. Johnston, 70,
The effect of preparation on lanthanum and lanthanum doped cobaltates for application in the water gas shift reaction M. O'Connell, K.G. Nickel, J. Pasel and R. Peters, 78,
The influence of catalyst geometry and topology on the kinetics of hydrocarbon hydrogenation reactions A.S. McLeod, 86,
Adsorption/desorption based characterisation of hydrogenation catalysts J.M. Kanewo, R.I. Slioor and A. O. I. Krause, 94,
Ethyl ethanoate synthesis by ethanol dehydrogenation S. W. Colley and M. W.M. Tuck, 101,
Observing heterogeneous catalysts at work: in-situ functional analysis of catalysts used in selective oxidation R. Schlögl, 108,
Reactions of 1,2-dichloroethene on Cu (110): cis versus trans isomer S. Haq, S.C. Laroze, C. Mitchell, N. Winterton and R. Raval, 121,
Aldol condensation of aldehydes and ketones over solid base catalysts G.J. Kelly and S.D. Jackson, 129,
Friedel-Crafts acylation and Fries rearrangement catalysed by heteropoly acids I. V. Kozhevnikov, J. Kaur and E. F. Kozhevnikova, 136,
Selective oxidation of propane on Cs2.5H1.5PV1WxMo11-xO40 heteropolyoxometallate compounds N. Dimitratos and J.C. Védrine, 145,
Multiphase hydrogenation reactors – past, present and future E.H. Stitt, R.P. Fishwick, R. Natividad and J.M. Winterbottom, 153,
Novel silica encapsulated metallic nanoparticles on alumina as new catalysts K.M.K. Yu and S.C. Tsang, 161,
Structure-transport relationships in the surface diffusion of molecules over heterogeneous surfaces within porous catalysts S.P. Rigby, 170,
Supported sulfonic acid catalysts in aqueous reactions S. Koujout and D.R. Brown, 178,
Pt/H-MOR and Pt/BEA catalysts with various Pt contents and bimetallic PtPd/H-MOR, PtIr/H-MOR and PtIr/H-BEA catalysts with various secondary metal contents for the hydroconversion of n-hexane A.K. Aboul-Gheit, S.M. Abdel-Hamid and A.E. Awadallah,
186,
Comparison of the acid properties on sulphated and phosphated silica-zirconia mixed oxide catalysts J.A. Anderson, B. Bachiller-Baeza and D. J. Rosenberg, 197,
Deactivation of the Pd-La/spinel catalyst for the preparation of 2,6-diisopropyl aniline J. Ruixia, X. Zaiku, Z. Chengfang and C. Qingling, 205,
Mn-containing thennostable multicomponent oxide catalysts of low-concentration methane mixture oxidation in air N.M. Popova, K.D. Dosumov, Z.T. Zheksenbayeva, L.V. Komashko, V.P. Grigoriyeva, A.S. Sass and R.K. Salakhova, 210,
Catalysts based on foam materials for neutralization of gas emissions A.N. Pestryakov, V. V. Lunin and N.E. Bogdanchikova, 216,
Highly active silica supported phosphotungstic acid catalyst for acylation reactions J.A. Gardner, G. Bond and R.W. McCabe, 221,
The effect of preparation variables on Pt and Rh/CexZrl-x02 water gas shift catalysts J.P. Breen, R. Burch and D. Tibiletti, 227,
Investigation of the acid-base properties of an MCM-supported ruthenium oxide catalyst by inverse gas chromatography and dynamic gravimetric vapour sorption F. Thielmann, M. Naderi, D. Burnett and H. Jervis, 233,
Development of novel supported Mo2C catalysts: carburization kinetics and optimal conditions T. H. Nguyen, Y. J. Lee, E. M. T. Yue, M. P. Brungs and A. A. Adesina, 240,
Keto-enol isomerism on transition metal surfaces, a denisty functional theory study R. Mann, G. J. Hutchings, W. van Rensburg and D. J. Willock, 247,
Direct transformation of methane to higher hydrocarbons in presence or absence of carbon monoxide J.L. Rico, J.S. J. Hargreaves and E.G. Derouane, 253,
Catalytic properties of Dawson-type heteropolyacids for alcohol dehydration and alkene isomerisation F. Donati and P. McMorn, 260,
Catalytic air oxidation of toluene in supercritical CO2 using solid supported surfactants containing Co(II) species J. Zhu, A. Robertson and S.C. Tsang, 266,
Selective hydrogenation reactions in ionic liquids K. Anderson, P. Goodrich, C. Hardacre and D. W. Rooney, 272,
Enatioselective hydrogenation of methyl pyruvate in the gas phase over cinchonidine-modified platinum N.F. Dunzrner, R.P.K. Wells, S.H. Taylor, P.B. Wells and G.J. Hutchings, 278,
Enantioselective hydrogenation of n-acetyl dehydrophenylanine methyl ester(NADPME) and some related compounds over alkaloid-modified palladium N.J. Caulfield, P. McMorn, P.B. Wells, D. Compton, K. Soars and G.J. Hutchings, 284,
Environmental catalysts: catalytic wet oxidation of different model compounds I.M. Castelo-Branco, S.R. Rodrigues, R. Santos and R.M. Quinta-Ferreira, 290,
Use of IR and XANES spectroscopies to study NOx storage and reduction catalysts under reaction conditions J.A. Anderson, B. Bachiller-Baeza and M. Fernández-García, 296,
Catalytic utilization of low-molecular alkanes S. I. Abasov, S.B. Agayeva and D. B. Tagiyev, 302,
Structure-activity relationships in N2O conversion over FeMFI zeolites. Preparation of catalysts with different distribution of iron species J. Pérez-Ramírez, A. Brückner, S. Kumar and F. Kapteijn, 308,
Subject Index, 314,
MODIFICATION OF CATALYSIS AND SURFACE REACTIONS BY SURFACE CARBON
Michael Bowker, Toseef Aslam, Chris Morgan, Neil Perkins
Centre for Surface Science and Catalysis, Dept. Chemistry, University of Reading, Reading RG6 6AD
1 INTRODUCTION
This paper is devoted to considerations of the role of surface carbon in modifying surface reactivity, an area to which Geoff Webb has contributed significantly during his career [1,2]. It is generally considered that surface carbon is a poison for many reactions. Indeed, in the strict sense this is usually true (that is, as carbon builds up on a surface and total activity goes down). However, in this paper we give some examples of surface reactivity which show that carbon can have a very positive role to play in manipulating reaction selectivity, so much so that it can result in higher activity to desired products.
Geoff...
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