The Application of Wave Functions Containing Interelectron Coordinates: II. The Ground State Energy of Atoms (Classic Reprint) - Hardcover

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Excerpt from The Application of Wave Functions Containing Interelectron Coordinates: II. The Ground State Energy of Atoms

In Sec. 2 of this paper, the general form of the hamiltonian is pre sented and discussed when the interelectron coordinates are introduced in addition to the radial and angular coordinates generally used. In Sec. 3, the separation of the hamiltonian into a perturbed and an unperturbed part is presented. The boundary conditions to be used on the radial and inter electron parts of the wave function are given in Secs. 4 and 5. The solu tion of the unperturbed wave equation under the boundary conditions imposed is easily carried out and the zero-order energy is obtained immediately.

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