Excerpt from Aec Computing and Applied Mathematics Center: Aec Research and Development Report
More recently, the development, by N. Ramsey and others, of I. I. Rabi's [1] molecular beam magnetic and electric resonance methods has given extremely precise measurements in the low energy radiofrequency range where the spectrum is produced by relatively weak interactions between the nuclei, the surrounding electronic charge cloud, and external magnetic or electric fields.
In principle, at least, all of these observations can be predicted, ab initio, from hypotheses concerning the particles involved and the laws of quantum mechanics but the mathematical complexity of the equations for even the simplest molecular system makes their solution a formidable task.
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